介孔分子筛MCM-41固载磷钨酸在苯乙酮苯甲酰腙合成中的应用  

Synthesis of Acetophenone Benzoyl Hydrazone Catalyzed by MCM-41 Immobilized H_3PW_(12)O_(40)(HWA)

作　　者：惠永海[1] 吴阳[1] Hui Yonghai Wu Yang(College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, Chin)

机构地区：[1]新疆大学化学化工学院,新疆乌鲁木齐830046

出　　处：《广东化工》2016年第21期4-4,23,共2页Guangdong Chemical Industry

基　　金：新疆大学本科生科研实践训练项目

摘　　要：文章介绍了苯乙酮苯甲酰腙化合物的合成方法,以苯乙酮和苯甲酰肼为起始原料,经过一系列反应条件的筛选,如,催化剂种类、催化剂用量、反应时间及底物配比等条件,最终确定最佳反应条件,并经1H MNR对目标化合物结构确认。本合成操作简单且收率很高,符合绿色化学的发展方向。The article simply introduced an approach to synthesize the acetophenone benzoyl hydrazone, was realized and manufactured from acclophenonc and benzoyl hydrazone. The yield of reaction was examined under variety reaction conditions, such as catalyst kinds, loading of catalysts, reaction time and ratio of reactants, et al. Finally, the optimum reaction conditions were determined. Moreover, the reaction was also found to easiness to handle up with high yield, and accords with the development tendency of green chemistry.

关 键 词：MCM-41 苯乙酮 苯甲酰肼 酰腙 合成 

分 类 号：O643.36[理学—物理化学]