磺酸功能化离子液体用于催化反应的最新进展  

Recent Advances in the Catalytic Application of Sulfonic Acid Functionalized Ionic Liquids

作　　者：郭亚楠[1] 郭芳杰[1] 陈平[1] Guo Ya＇nan Guo Fangjie Chen Ping(College of chemistry and material Science Engineering, Liaoning Shihua University ,Fushun Liaoning 113001, China)

机构地区：[1]辽宁石油化工大学化学与材料科学学院,辽宁抚顺113001

出　　处：《辽宁石油化工大学学报》2016年第3期1-7,共7页Journal of Liaoning Petrochemical University

基　　金：国家自然科学基金项目(21071073);辽宁省自然科学基金项目(2015020196)

摘　　要：磺酸功能化离子液体是指在有机阳离子中引入一个或多个磺酸基(—SO3H),或者阴离子为磺酸的Brnsted(B酸)型离子液体,其酸性强、极性大、活性高。简要介绍了磺酸功能化离子液体的合成方法,详细阐述了在多种有机催化反应中的应用,展望了磺酸功能化离子液体的发展前景。Sulfonic acid functionalized ionic group （-SO3 H） introduced into the organic liquid is a type of Bronsted acid-（B acid） ionic liquid with one or more sulfonic cation or the anion. This type of ionic liquid shows strong acidity, high polarity and intense activity. In this paper, the synthesis of sulfonic acid functionalized ionic liquid is reviewed, and the application in many kinds of organic catalytic reactions is also described in details. Moreover, the perspectives of sulfonic acid functionalized ionic liquid has been discussed.

关 键 词：磺酸功能化离子液体 催化 酰化 酯化 应用 

分 类 号：O621.25[理学—有机化学]