二氧化碳甲烷自热重整计算分析与中试  

Calculation analysis and pilot test of CO_2-CH_4 autothermal reforming

作　　者：刘俊义 常卉 祝贺[2] 唐志永[2] 

机构地区：[1]山西潞安煤基合成油有限公司 [2]中国科学院上海高等研究院低碳转化科学与工程重点实验室

出　　处：《石油与天然气化工》2016年第6期25-31,共7页Chemical engineering of oil & gas

基　　金：中国科学院先导项目"低阶煤清洁高效梯级利用关键技术与示范"(XDA07000000);国家科技支撑计划"CO2化工利用关键技术研发与示范"(2013BAC11B00)

摘　　要：运用Gibbs自由能最小化方法和耦合详细反应动力学的计算流体力学(CFD)方法对CO_2-CH_4自热重整进行了相关的计算分析。结合自主研发的反应器和催化剂,在山西省潞安集团煤制油低碳循环经济园区进行了原料气处理量10 000m^3/h、运行压力2MPa、新型镍基催化剂装填量约5t的中试实验,获得合成气中甲烷摩尔分数小于1%、n(H_2)/n(CO)=1.1、有效气摩尔分数为60.7%的合成气。其中,CO_2-CH_4自热重整反应器设计主要尺寸为:内径1.6m,燃烧高度3.0m,催化剂装填高度2.8m,反应器总体高度约13.8m。The CO2-CH4 autothermal reforming process is calculated and analyzed by the Gibbs free energy minimization method and Computational Fluid Dynamics （CFD） coupled with detailed reaction kinetics. Combining with independent research and development reactors and catalysts, the pilot test conditions were the raw material gas treatment capacity of 10 000 m^3/h, operating pressure of 2 MPa, nickel based catalyst loading of about 5 tons, and the syngas was CH4/syngas ratios less than 1%, n （H2）/n（CO） =1.1 and effective gas content of 60.7% on the Low Carbon Circular Economy Park, Shanxi Lu＇an Coal-to-Gasoline Co., Ltd. The main design dimensions of CO2-CH4 autothermal reforming reactor were the inner diameter of 1.6 m, the combustion height of 3.0 m, the catalyst loading height of 2.8 m and the reactor overall height of about 13.8 m.

关 键 词：二氧化碳 甲烷 合成气 自热重整 Gibbs 计算流体力学 反应器 中试 

分 类 号：TE665.3[石油与天然气工程—油气加工工程]