富勒烯二聚体的结构及电化学性质研究进展  

Structure and Electrochemical Property of Fullerene Dimers

作　　者：常伟伟[1] 赵增典[1] 

机构地区：[1]山东理工大学分析测试中心,淄博255049

出　　处：《有机化学》2016年第11期2651-2661,共11页Chinese Journal of Organic Chemistry

基　　金：山东省中青年科学家科研奖励基金(No.BS2015CL011)资助项目~~

摘　　要：富勒烯二聚体由于其独特的结构及优异的性质在国际上引起了持续而广泛的关注.目前已被合成分离出近百种二聚体化合物,包括单键相连的富勒烯二聚体、含有活性连接基团的二聚体、全碳富勒烯二聚体和不对称的富勒烯二聚体等.这些新的分子体系具有优异的光电性质,有望在人工光合成、新型光电子器件及超分子化学中得到重要应用.就近年来研究报道的富勒烯二聚体进行了归纳分类,介绍了其结构形式、电化学性质,并对未来的发展方向进行了展望.Fullerene dimers have attracted extensive attention due to their unique structures and fascinating properties. Hun- dreds of fullerene dimers have been isolated so far, including the singly-bonded fullerene dimers, fullerene dimers connected by electroactive bridges, all-carbon fullerene dimers and unsymmetrical dimers, etc. These new molecular systems have poten- tial applications in the area of artificial photosynthesis, photoelectronic device and supramolecular chemistry. Based on the different structure types, various fullerene dimers reported are summarized and classified in this review. Furthermore, the elec- trochemistry property of the dimers is discussed and the research trend of this area is also prospected.

关 键 词：富勒烯 二聚体 电化学 

分 类 号：O613.71[理学—无机化学]