2-甲基氮杂环丙烷与CO_2的环加成反应  

Cycloaddition reaction of 2-methyl-aziridine aziridine and CO_2

作　　者：孙志琴[1] 张伟 

机构地区：[1]山西职工医学院,山西晋中030619 [2]榆次区人民医院,山西晋中030600

出　　处：《化学研究》2016年第6期704-706,共3页Chemical Research

摘　　要：采用碱金属卤化物和季铵盐作为催化剂在温和条件下催化2-甲基氮杂环丙烷的CO2环加成反应,得到区域选择性的4-甲基-2-噁唑烷酮.实验结果表明,该合成路线具有反应条件温和、收率高、区域选择性好、操作简单、对环境安全友好等特点.A cycloaddition reaction of 2-methyl-aziridine and CO_2 was successfully catalyzed by alkali metal halide or tetraalkylammoniumhalide with mild conditions to give 4-methyl-2-oxazolidone.Finally,the optimized reaction condition has the characteristics of high yield,good regioselectivity,mild and simple operation and being environmentally-friendly.

关 键 词：氮杂环丙烷 环加成反应 噁唑烷酮 

分 类 号：TQ252.9[化学工程—有机化工]