基于离子液体的石墨烯及其复合物制备的研究进展  

Research progress in preparation of graphene and its composites based on ionic liquids

作　　者：杨胜凯[1] 王春风[1] 张松娜 卓克垒[1] Shengkai Yang Chunfeng Wang Songna Zhang Kelei Zhuo(Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education,School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang 453007, Chin)

机构地区：[1]河南师范大学化学化工学院,绿色化学介质与反应教育部重点实验室,精细化学品绿色制造河南省协同创新中心,新乡453007

出　　处：《中国科学：化学》2016年第12期1277-1291,共15页SCIENTIA SINICA Chimica

基　　金：国家自然科学基金(编号:21173070,21303044,21573058)资助项目

摘　　要：石墨烯需求量日益增加,有关其制备方法的研究已有大量文献报道.咪唑类离子液体与石墨烯间的特殊作用,使得离子液体参与制备石墨烯成为很有潜力的方法.本文对离子液体参与石墨烯及其复合物制备的研究进展进行了综述.在论述了制备机理的基础上,系统总结了离子液体参与的各种制备方法,评判了各种方法的优缺点,重点关注了离子液体在其中所起的作用,指出了最有潜力的离子液体应具备的结构特点,对开发基于离子液体的石墨烯及其复合物制备方法的研究具有一定的指导作用.Demands for graphene are increasing and thus some preparation methods of it have been reported widely. The special interactions between ionic liquids and graphene make the ionic liquids a class of promising substances in the preparation of graphene and its composites, and some important developments in this field have been obtained. Here, the research progress on the preparation of graphene and its compositions is reviewed. Firstly, the preparation methods are classified and the preparation mechanism is introduced. Secondly, various preparation methods are summarized and their advantages and disadvantages are also evaluated. Finally, research trends for the preparation methods are pointed out. The review may provide a guidance to exploring the preparation methods of graphene and its composites.

关 键 词：石墨烯 复合物 离子液体 制备 机理 

分 类 号：TQ127.11[化学工程—无机化工] TB33[一般工业技术—材料科学与工程]