新型氮杂杯[4]芳烃衍生物的合成  

Synthesis of novel azacalix[4]arene derivatives

作　　者：蒋忠良[1] 卢超[1] 段辉[1] 

机构地区：[1]同济大学化学科学与工程学院,上海200092

出　　处：《精细与专用化学品》2016年第12期32-34,共3页Fine and Specialty Chemicals

摘　　要：以对叔丁基杯[4]芳烃为原料,对其下沿的酚羟基进行化学修饰,通过取代、加氢脱苄基等反应合成了尚未见报道的新型氮杂杯[4]芳烃衍生物。其结构经1 HNMR,13 CNMR和HRMS(ESI)表征。Using p-tert-butylcalix[4]arene as starting materials, a novel azacalix[4]arene derivates which have not been reported were synthesized by the chemical modification of phenol hydroxyl in the lower rim. Substitution reaction and hydrogenation-debenzylation were adopted to obtain the target compounds. The structure of these corn pounds were characterized by 1 HNMR, 13CNMR and HRMS（ESI）.

关 键 词：杯[4]芳烃衍生物 含氮基团 合成 

分 类 号：O625.1[理学—有机化学]