meso-四(1-萘)金属卟啉的合成及荧光性质研究  

Synthesis and Fluorescence Properties of a Naphthalene Metal Porphyrin

作　　者：盛宁[1] 管美惠 曹厚勇 万杨[1] 罗浩[1] SHENG Ning GUAN Meihui CAO Houyong WAN Yang LUO Hao(Department of Chemistry and Chemical Engineering, Jining University, Qufu 273155, China)

机构地区：[1]济宁学院化学与化工系,山东曲阜273155

出　　处：《济宁学院学报》2016年第6期43-45,共3页Journal of Jining University

基　　金：国家自然科学基金青年基金(21401075);山东省高等学校科技计划项目(J15LC57);济宁学院教学改革研究项目(JX201507)

摘　　要：卟啉及其化合物是一类广泛存在于自然界中并具有特殊生理活性的化合物,它们通常具有较高的化学稳定性、热稳定性及独特的光、电、磁等性质,这使其在新型的分子杂化、分子识别、分子导体、分子电子元器件等方面拥有广阔的前景.采用溶剂热法成功合成了meso-四(1-萘)铅卟啉和meso-四(1-萘)钴卟啉,并对其进行紫外表征和荧光性质的研究.Porphyrins and their compounds are a class physiological activity, they usually have higher chemical of compounds widely exist in nature and have a special stability, thermal stability and unique optical, electrical, magnetic and other properties, which make them in applications of molecular recognition, molecular conductor, and molecular electronic devices etc. In this article, the 1-naphthyl substituted lead porphyrin and 1-naphthyl substituted cobah porphyrin were synthesized using solvothermal method, purified by column chromatography. The two metal porphyrins were characterized by UV-Vis spectra, the fluorescence properties of them were studied by fluorescence spectrophotometer. The results showed that both of the metal porphyrins have good fluorescence properties.

关 键 词：金属卟啉 合成 溶剂热法 荧光 

分 类 号：O614[理学—无机化学]