不同载体的固体酸催化剂对糠醛渣水解制乙酰丙酸催化性能的影响  

Catalytic Performance of Catalysts with Different Supports for Pyrolysis of Furfural Residue to Levulinic Acid

作　　者：徐海燕[1,2] 任素霞[1,2] 杨延涛[3] 雷廷宙[2,4] 朱金陵[1,2] 

机构地区：[1]河南省科学院能源研究所有限公司,郑州450008 [2]河南省生物质能源重点实验室,郑州450008 [3]河南农业大学机电工程学院,郑州450008 [4]河南省科学院,郑州450008

出　　处：《河南科学》2016年第12期2007-2011,共5页Henan Science

基　　金：国家科技支撑计划项目(2014BAD02B05);河南省科技攻关计划项目(162102210144);河南省基础与前沿技术研究计划项目(132300413218)

摘　　要：首先用一步法合成了一种介孔分子筛,然后分别以常规微孔分子筛ZSM-5、介孔分子筛SBA-15以及自制分子筛为载体制备了三种不同载体负载的TiO_2/SO_4^(2-)固体酸催化剂.以糠醛渣为原料,研究了三种不同载体负载的TiO_2/SO_4^(2-)固体酸催化剂对纤维素水解制乙酰丙酸催化性能的影响,在相同的反应条件下自制载体负载的TiO_2/SO_4^(2-)催化剂显示了较好的催化性能.在优化的反应条件下,反应温度在220℃、反应时间60 min、固体酸用量10%左右、液固比15∶1,自制载体催化剂乙酰丙酸收率可以达到72.3%.Mesoporous molecular sieve with strong acidity was prepared during a simple one step synthesis procedure. Three TiO2/SO4^2- soliod catalysts were synthesized using ZSM-5, SBA-15 and self-made molecular sieve as support respectively, and the catalytic performance of the resulting catalysts was examined in pyrolysis of fuffural residue to levulinic acid. The catalyst synthesised a using disordered worm-like mesoporous molecular sieve as support which showed higher conversion of cellulose to levulinic acid than those of traditional microporous or mesoporous molecular sieve. The experiment was optimized the process conditions ： hydrolysis temperature was 220℃, hydrolysis time was 60 min, the amount of solid acid was 10%, and water-materials mass ratio was 15 ： 1. Under this condition, the LA yield could reach 72.3%.

关 键 词：乙酰丙酸 水解 糠醛渣 催化剂 

分 类 号：TK6[动力工程及工程热物理—生物能]