meso-位咔唑基取代的二吡咯甲烷的合成与表征  

Synthesis and Characterization of meso-Carbazole Dipyrromethane

作　　者：廖俊旭[1] 谢泽川 谢靖飞 郭一祺 宗乔 彭敏[1] 赵鸿斌[1] LIAO Jun-xu XIE Ze-chuan XIE Jing-fei GUO Yi-qi ZONG Qiao PENG Min ZHAO Hong-bin(School of Chemical Engineering and Energy Technology, Dongguan University of Technology, Dongguan 523808, Chin)

机构地区：[1]东莞理工学院化学工程与能源技术学院,广东东莞523808

出　　处：《精细化工中间体》2016年第5期38-40,47,共4页Fine Chemical Intermediates

基　　金：广东省自然科学基金(2016A030313128)

摘　　要：设计合成了一种meso-位咔唑基取代的二吡咯甲烷,并通过~1H NMR、^(13)C NMR和MALDI-TOFMS等手段对其进行了结构表征。对其合成方法进行了探讨,优化了实验条件。此二吡咯甲烷衍生物的合成方法具有普适性,可应用于不同类型二吡咯甲烷衍生物的合成。实验结果表明,合成路线简洁,反应条件温和、收率达90.1%。The meso-carbazole dipyrromethane was designed and synthesized, and its structure was characterized using ^1H NMR,^13C NMR, and MALDI-TOF-MS. The synthetic method was explored, and the reaction conditions were optimized. The synthetic strategy proposed in this paper was universal, and could be applied for the different types of dipyrromethane derivatives. This synthetic route was simple and mild, and high yield of up to 90.1%could be obtained.

关 键 词：二吡咯甲烷 高效合成 结构表征 

分 类 号：TQ251.3[化学工程—有机化工]