石墨烯基环氧树脂复合热界面材料的制备及热性能  

Preparation and Thermal Performance of Graphene Modified Epoxy Resin

作　　者：唐波[1] 许继星[1] 黄维秋[1] TANG Bo XU Jixing HUANG Weiqiu(Jiangsu Provincial Key Laboratory of Oil ＆ Gas Storage and Transportation Technology, Changzhou University, Changzhou 213016, Jiangsu, China)

机构地区：[1]常州大学,江苏省油气储运技术重点实验室,江苏常州213016

出　　处：《硅酸盐学报》2017年第1期126-131,共6页Journal of The Chinese Ceramic Society

基　　金：国家自然科学基金项目(51506012);江苏省高校“青蓝工程”计划项目(SCZ1409700002);江苏省科技成果转化专项资金项目(BA2015166);江苏省自然科学基金项目(BK20150266);常州市基础研究科技资助计划项目(CJ20159032)

摘　　要：采用氧化还原法制备的石墨烯作为改性材料,研究石墨烯的含量及其还原程度对环氧树脂热导率的影响,并进一步测定复合热界面材料的热导率在高温下的稳定性。结果表明:石墨烯可以大幅提高环氧树脂的热导率,加入质量分数为15%的石墨烯可以使环氧树脂的热导率提高2 300%。石墨烯表面的剩余官能团对产物的热导率也有显著的影响,表面官能团可以充当声子输运通道并减小界面间的Kapitza热阻,但是过多的表面官能团会减小石墨烯的本征热导率。另外,通过优化石墨烯的还原程度及尺寸,提高了复合材料产物热导率在高温下的稳定性。Reduced graphene oxide （RGO） nanosheets were adopted as a modifier to improve the thermal conductivity of epoxy resin （ER）, and the influences of the content and reduction degree of the RGO nanosheets on the thermal properties of thermal interface materials （TIMs） were investigated. The results demonstrate that the thermal conductivity increases 2 300% after adding 15% RGO nanosheets into ER. Moreover, the thermal conductivity of the resultant composite is closely related to the residual amount of surface functional groups of the RGO. The presence of surface functional groups can act as a bridge to improve the phonon transport between graphene basic plane and ER, and reduces the Kapitza resistance. However, excessive surface functional groups could reduce the intrinsic thermal conductivity of graphene. The thermal conductivity of TIMs increases, and the thermal property of the TIMs at high temperatures becomes more stable at optimized average size and reduction time of the RGO.

关 键 词：热界面材料 石墨烯 KAPITZA热阻 环氧树脂 表面官能团 

分 类 号：TB332[一般工业技术—材料科学与工程]