N-对甲苯磺酰-5-氨基间苯二甲酸构筑的一维配位聚合物的合成、晶体结构和荧光性质  

Syntheses, Crystal Structures and Fluorescent Properties of One-Dimensional Coordination Polymers with N-p-Tolylsulfonyl-5-aminoisophthalic Acid

作　　者：黄妙龄[1,2] 吴文士[1] 陈婉贞[2] HUANG Miao-Ling WU Wen-Shi CHEN Wan-Zhen(College of Materials Science and Engineering, Huaqiao University, Xiamen, Fujian 361000, China College of Chemical Engineering and Materials, Quanzhou Normal University, Quanzhou, Fujian 362000, China)

机构地区：[1]华侨大学材料科学与工程学院,厦门361000 [2]泉州师范学院化工与材料学院,泉州362000

出　　处：《无机化学学报》2017年第1期66-72,共7页Chinese Journal of Inorganic Chemistry

基　　金：福建省教育厅基金(No.JA14261);国家大学生创新创业训练(No.201610399007)资助项目

摘　　要：采用普通溶液法和水热法分别合成了2个金属-有机配位聚合物:{[Cu(Ts-5-AIPA)(phen)(H_2O)]·H_2O}n(1)和[Cd(Ts-5-AIPA)(phen)]n(2)(Ts-5-AIPA=N-对甲苯磺酰-5-氨基间苯二甲酸根,phen=菲咯啉),并用红外光谱、热重和X射线单晶衍射对配合物的结构进行了表征。结果表明:2个配合物均为单斜晶系,配合物1为P21/c空间群,配合物2为C2/c空间群;2个配合物均为一维链状结构,再通过氢键和π-π堆积作用形成三维超分子结构。另外,还研究了2个配位聚合物的荧光性质。Two metal-organic coordination polymers, {[Cu（Ts-5-AIPA）（phen）（H20）I ·H20）· （1） an（Ts-5-AIPA=N-X （phen）] （2） （Ts-5-AIPA=N-p-tolylsulfonyl-5-aminoisophthalie acid radical, phen=phenanthroline）, were synthesized using common solution method and hydrothermally method, respectively. Their crystal structures were determined by IR, TG and single-crystal X-ray diffraction. Two complexes crystalize in monoclinic system, space group P21/c for complex 1 and C2/c for complex 2. They are one-dimensional chain structure, and further extended into a three-dimensional supramolecular structure through hydrogen bonds and π-π interactions. In addition, fluorescent properties of two complexes were investigated. CCDC： 839135, 1; 1472441, 2.

关 键 词：配位聚合物 N-对甲苯磺酰-5-氨基间苯二甲酸 晶体结构 荧光 

分 类 号：O614[理学—无机化学]