光催化膜分离工艺处理混凝废水的研究  

Study on Treatment of Coagulation Wastewater by Photocatalytic Membrane Separation Process

作　　者：王汉斌[1] 宋宏臣[2] 王建明[2] 张德华[1] 

机构地区：[1]昆明理工大学环境科学与工程学院,云南昆明650000 [2]广州中国科学院先进技术研究所,广东省膜材料与膜分离重点实验室,广东广州511458

出　　处：《水处理技术》2017年第1期72-76,共5页Technology of Water Treatment

基　　金：国家自然科学基金项(21307146);广东省产学研合作项目(2015B090901018);广州市珠江科技新星专项(201506010024)

摘　　要：采用光催化膜分离耦合工艺处理混凝废水。首先通过相转化法自制二氧化钛(TiO_2)改性聚偏氟乙烯(PVDF)光催化超滤膜;然后通过傅里叶红外光谱(FTIR)、扫描电子显微镜(SEM)、接触角测试仪、自制光催化膜分离工艺装置对膜结构、膜表面亲疏水性以及膜光催化和过滤性能进行测试分析;并通过改变进水流速、溶液pH,分析光催化膜分离工艺处理混凝废水的特点。研究结果表明,TiO_2成功嵌入到PVDF膜中,改性后膜接触角减小,具有一定的的光催化性能和更好的过滤性能。在混凝废水的处理过程中,进水流速主要影响膜通量,pH主要影响截留率,但光催化对膜分离过程的改进效果并不受工艺参数的影响。Photocatalytie membrane separation process was used to treat coagulation wastewater. At first, the TiO2 modified poly （vinyl fluoride） （PVDF） photocatalytle ultrafiltration membrane was prepared by phase inversion method. The structure, surface hydrophilic and hydrophobic, photocatalytic and filtration performance were by fourier infrared spectroscopy （FTIR）, scanning electron microscopy （SEM）, contact angle meter and photocatalysis-membrane separation coupling devices. And the characteristics of the photocatalytic membrane separation process were analyzed by changing the influent rate and pH. Results indicated that： TiO2 was embed in the PVDF membranes successfully, the modified membrane had smaller contact angle, and the membrane had catalytic performance and better filtration performance. In the treatment of coagulation wastewater, the influent flow rate mainly affected the membrane flux, and the pH value mainly affected the rejection rate, but the photocatalytic improvement of the membrane separation process was not affected by the process parameters.

关 键 词：甲基橙 混凝 光催化 膜分离 

分 类 号：TQ028.8[化学工程] TU991.2[建筑科学—市政工程]