一种平面Pd(Ⅱ)配合物的合成结构以及光催化性质的研究  

Synthesis,Structure and Photopcatalytic Properties of a Planar Pd(Ⅱ) Complex

作　　者：展阳 苏俊琪[1] 高恩军[1] 

机构地区：[1]沈阳化工大学配位化学研究室,辽宁省无机分子基化学重点实验室,辽宁沈阳110142

出　　处：《当代化工》2016年第12期2721-2723,共3页Contemporary Chemical Industry

基　　金：国家自然科学基金项目,项目号:21671138

摘　　要：配合物[Pd(dmphen)CO3]·H2O(dmphen是2,9-二甲基-1,10-菲咯啉)已合成和表征。钯配合物是采用水热合成法制备的,利用X射线单晶衍射法、元素分析、红外等方法对其进行表征。本文以亚甲基蓝(MB)为探针进行了光催化反应对其进行降解,测评了[Pd(dmphen)CO3]·H2O配合物的光催化降解活性。结果表明,在300 W氙灯光源照射下,该配合物对亚甲基蓝光的催化降解有一定效果,亚甲基蓝(MB)的光催化降解率由时间和Pd配合物的参与共同决定。The complex [Pd（dmphen）CO3]·H2O（dmphen is 2,9-dimethyl-1,10-phenanthroline） have been synthesized by hydrothermal reaction.Elemental analysis, IR and single-crystal X-ray diffraction were used to characterize the Pd（II）complex. The photocatalytic degradation of methylene blue was used as a reaction probe to evaluate Pd（II）complex photocatalytic degrading activity. The results show that the complex has effect on catalytic degradation of methylene blue under the 300 W xenon light.The photocatalytic degaration rate of methylene blue was determined by the catalysis time and the participation of Pd complex.

关 键 词：钯配合物 水热合成 光催化 亚甲基蓝 降解 

分 类 号：TQ028[化学工程]