苯甲醚超高交联吸附树脂的合成及吸附性能  

Synthesis and Adsorptive Property of Anisole Hypercrosslinked Adsorption Resin

作　　者：金秋[1] 姜松[1] 樊素芳[1] 

机构地区：[1]河南农业大学理学院,河南郑州450002

出　　处：《宁夏大学学报（自然科学版）》2016年第4期461-465,共5页Journal of Ningxia University(Natural Science Edition)

基　　金：国家自然科学基金资助项目(21004055)

摘　　要：用苯甲醚与氯甲醚聚合交联,得到苯甲醚超高交联吸附树脂ZT.红外及比表面测定表明,ZT的比表面积为104.63m2/g.比较ZT,XAD-4对苯胺和苯酚的吸附性能,ZT对苯酚的吸附为放热过程,对苯胺的吸附为吸热过程;苯胺和苯酚的吸附均在200min左右达到吸附平衡.相同条件下,ZT对苯胺、苯酚的吸附量分别是XAD-4的2倍和1.56倍.The polymerization cross-linking reaction between anisole and chloromethyl ether produces anisole hypercrosslinked adsorption resin ZT.The infrared and specific surface measurement shows that,the specific surface area of ZT is 104.63m2/g.Comparing with the adsorptive properties of ZT,XAD-4on aniline and phenol,the adsorption of ZT on phenol is exothermic process,and endothermic process on aniline;the adsorption on aniline and phenol reaches adsorption balance at around 200 min.The adsorbing capacity of ZT on aniline and phenol is twice and 1.56 times of that of XAD-4under same condition.

关 键 词：苯甲醚 超高交联树脂 傅-克反应 苯胺 苯酚 吸附 

分 类 号：O647.3[理学—物理化学]