光催化制备1,3,5,7-四氯金刚烷的合成工艺  

Synthesis of 1,3,5,7-tetrachloroadamantane under Photocatalysis

作　　者：刘田英 王艳红[1] 曹端林[1] 王建龙[1] 李永祥[1] 罗军[2] LIU Tian-ying WANG Yan-hong CAO Duan-lin WANG Jian-long LI Yong-xiang LUO Jun(School of Chemical Engineering and Environment, North University of China1 , Taiyuan 030051 , P. R. China School of Chemical Engineering, Nanjing University of Science and Technology2 , Nanjing 210094, P. R. China)

机构地区：[1]中北大学化工与环境学院,太原030051 [2]南京理工大学化工学院,南京210094

出　　处：《科学技术与工程》2017年第2期208-210,共3页Science Technology and Engineering

基　　金：山西省青年自然科学基金(2015021056);青年科技创新项目(QKCZ-jp-2015-02)资助

摘　　要：以金刚烷为原料,四氯化碳为溶剂光催化反应成功制备了1,3,5,7-四氯金刚烷,该工艺路线操作简单、节能环保,大大减少了催化剂的使用量,无须加热回流,反应时间短。目标产物通过熔点,红外光谱、显微镜等测试手段对结构与形貌进行了表征分析,讨论了不同光源对实验结果的影响。A novel synthetic method of 1,3,5,7-tetrachloroadamantane has been achieved under photocatalysis condition. This process had more advantages than the traditional,such as mild reaction conditions,short reaction time,green chemistry environment-friendly. The main product was characterized by melting point,IR and microscope. The influence of different light source on experiment was discussed.

关 键 词：1 3 5 7-四氯金刚烷 光催化 氯代反应 

分 类 号：TJ55[兵器科学与技术—军事化学与烟火技术] O62[理学—有机化学]