μ-氧桥联双核金属卟啉合成方法的比较  

A Comparison Study of Synthesizing Methods of μ-Oxygen Bridge Binuclear Metalloporphyrin

作　　者：邱晓航[1] 潘雨辰[1] 高林寒 刘晓彤[1] 王庆伦[1] 任红霞[1] Qiu Xiaohang Pan Yuchen Gao Linhan Liu Xiaotong Wang Qinglun Ren Hongxia(College of Chemistry, Nankai University, Tianjin, 300071, China)

机构地区：[1]南开大学化学学院,天津300071

出　　处：《南开大学学报（自然科学版）》2016年第6期8-13,共6页Acta Scientiarum Naturalium Universitatis Nankaiensis

基　　金：中央高校基本科研业务费专项资金(65011601);国家基础科学人才培养基金(J1103306)

摘　　要：合成了4种μ-氧桥联双核金属卟啉,并对包括中间产物在内的几种物质进行表征.同时比较了其对应的合成方法,即一步法和分步法,并就一步法的优越性加以论述.Four kinds of μ-oxygen bridge binuclear metalloporphyrin were synthesized,and several compounds,including intermediate products and final products,were charaterized by ~1H NMR and FTIR.The two synthetic methods,one-step and fractional step method,were compared simultaneously,and the advantages of one-step method were discussed.

关 键 词：μ-氧桥联双核金属卟啉 一步法 分步法 

分 类 号：O631.1[理学—高分子化学]