磺胺二甲基嘧啶对镉在针铁矿上吸附行为的影响  

Influences of sulfamethazine on adsorption of cadmium on goethite

作　　者：唐婷[1] 杨琛[1,2] 王丽[1] 党志[1,3] TANG Ting YANG Chen WANG Li DANG Zhi(College of Environmental and Energy, South China University of Technology, Guangzhou 510006 Guangdong Environmental Protection Key Laboratory of Solid Waste Treatment and Recycling, Guangzhou 510006 Key Laboratory of Pollution Control and Ecosystem Restoration in Industry Clusters, Ministry of Education, Guangzhou 510006)

机构地区：[1]华南理工大学环境与能源学院,广州510006 [2]固体废物处理与资源化广东省环境保护重点实验室,广州510006 [3]工业聚集区污染控制与生态修复教育部重点实验室,广州510006

出　　处：《环境科学学报》2017年第2期602-609,共8页Acta Scientiae Circumstantiae

基　　金：国家高技术研究发展计划("863"项目)(No.2013AA062609);国家自然科学基金(No.41173104)~~

摘　　要：环境中抗生素与重金属的共存会使各自在土壤中的迁移转化和生态效应变得更为复杂,为了准确评估磺胺二甲基嘧啶(SMT)与重金属镉复合污染下的环境风险,采用紫外光谱法,研究了中性条件下磺胺二甲基嘧啶与镉的络合特性;采用批量振荡吸附平衡法,研究了SMT存在的条件下针铁矿对镉的吸附特性.结果表明:SMT与镉有一定的络合能力,络合常数log K值为-3.31;针铁矿对SMT和镉都有一定的吸附作用;在SMT存在条件下,针铁矿对镉的吸附容量明显增强,这可能是由于SMT改变了针铁矿表面带电情况,红外结果表明在吸附过程中形成了针铁矿-SMT-镉三元络合物.因此,在评估抗生素与重金属复合污染的环境影响时,需要考虑到污染物之间的协同效应.The coexistence of antibiotics and heavy metals might lead to complicated transport behaviors and ecological effects in the environment. UV-Vis method was employed to investigate the complexation between sulfamethazine（ SMT） and Cd（ II） at neutral condition. Results showed that SMT exhibited certain complexation ability to cadmium and the binding constant（ log K） was about-3.31. The results of batch adsorption equilibrium experiments showed that both of SMT and Cd^2＋could be adsorbed on the surface of goethite and the sorption capacity of Cd2＋on the goethite could be enhanced by SMT in a certain concentration range. It might be due to the fact that adsorbed SMT could neutralize the positive charge of goethite. FTIR results showed the specific ternary complex of goethite-SMT-Cd^2＋might be formed on the surface. The synergic adsorption of co-contaminants should be considered to assess the risk of antibiotic drugs and heavy metal pollution in the environment.

关 键 词：抗生素 重金属 针铁矿 吸附 复合污染 

分 类 号：X703[环境科学与工程—环境工程]