9-蒽醛对甲氧基苯甲酰腙及铜配合物合成与晶体解析  

9-Anthraldehyde P-Anisic Hydrazide and Copper Complexes Synthesis and Crystal Analysis

作　　者：张强[1] 董丽芳[1] 刘娥[1] 王雪[1] 

机构地区：[1]青岛科技大学,山东青岛266042

出　　处：《山东化工》2017年第2期18-20,共3页Shandong Chemical Industry

摘　　要：酰腙是一类含有酰胺键(-CONH-)的特别希夫碱。由于协调的各种形式,具有较强的协调能力,以及广泛的医学和生物学活性的非线性光学性质,已引起广泛的关注,结果被广泛应用在催化,材料分析和光电。本文主要探究新型酰腙及其配合物的合成及其结构表征。醛、甲氧基苯甲酰肼的缩合反应,合成新的酰腙甲氧基苯甲酰腙,及其配体与醋酸铜配位反应,金属配合物的合成。通过红外光谱和单晶衍射对其进行结构表征,研究说明配合物为烯醇式配位。Hydrazone is a kind of amide （ - CONH - ） special Schiff base. Because of the various forms of coordination, strong coordination ability, nonlinear optical properties and a wide range of medical and biological activity, has aroused widespread concern, the results are widely used in catalysis, analysis and photoelectric materials. Synthesis and structure characterization of this dissertation mainly explores new hydrazonecomplexes. The aldehyde and methoxy benzoyl hydrazine condensation reaction synthesis of new acylhydrazones methoxy benzoyl hydrazone, and its ligand and copper acetate coordination reaction, synthesis of metal complexes. Through infrared spectroscopy and X - ray diffraction were characterized for its, studies show that complexes as enolate ligand.

关 键 词：酰腙 希夫碱 配合物 生物活性 进展 

分 类 号：TQ016.1[化学工程]