A Mild and Rapid Synthesis of （Z）-β-Sulfonyl Enoates from Sodium Sulfinates and Propargyl Esters  

作　　者：Jun Jiang Huaxu Zou Niannian Yi Ruijia Wang Hao Zhang Lixin Lan Jiannan Xiang 

机构地区：[1]State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha, Hunan 410082, China [2]Hunan Chemical Vocational Technology College, Zhuzhou, Hunan 412000, China

出　　处：《Chinese Journal of Chemistry》2016年第12期1245-1250,共6页中国化学（英文版）

摘　　要：Water-promoted sulfonylation of propargyl esters leading to highly regioselective and stereoselective formation of （Z）-β-sulfonyl enoates in excellent yields, by a simple, mild, rapid and environmentally benign reaction proce- dure is reported.Water-promoted sulfonylation of propargyl esters leading to highly regioselective and stereoselective formation of （Z）-β-sulfonyl enoates in excellent yields, by a simple, mild, rapid and environmentally benign reaction proce- dure is reported.

关 键 词：sodium sulfinates propargyl esters green reaction （Z）-β-sulfonyl enoates 

分 类 号：TQ423.114[化学工程] O621.3[理学—有机化学]