连续本体法制备ABS树脂工艺优化研究  

Study on Technological Optimization for ABS Resin Prepared by Continuous Bulk Polymerization

作　　者：周川 王益波 袁博 申凯华[2] 

机构地区：[1]中国兵器北方华锦化学工业集团有限公司,辽宁盘锦124021 [2]大连理工大学精细化工国家重点实验室,辽宁大连116024

出　　处：《中国塑料》2017年第2期27-33,共7页China Plastics

摘　　要：利用自主研发的串联管式平推流本体丙烯腈-丁二烯-苯乙烯共聚物(ABS)中试装置,以现有的中抗冲牌号产品为基础,通过改变反应温度、引发剂和链转移剂加入量等工艺参数,研究产品的接枝率、相对分子质量、橡胶粒径等微观性能的变化对产品冲击性能的影响,进而实现通过优化工艺条件来提升产品性能的目的。结果表明,经过优化后,产品冲击强度由160 J/m提高到221 J/m。ABS resin was synthesized by continuous bulk polymerization in a self-developed plug flow reactor, and effects of process parameters including reaction temperature, concentration of initiator, concentration of chain transfer agent on the grafting ratio, molecular weight and particle size of the resultant ABS resin were investigated. The relationship between impact strength and microstructure was also studied. On the basis of the results, the synthetic technology for ABS was optimized, and the impact strength of ABS products was improved from 160 J/m to 221 J/m.

关 键 词：丙烯腈-丁二烯-苯乙烯共聚物 连续本体法 工艺优化 冲击强度 

分 类 号：TQ325.2[化学工程—合成树脂塑料工业]