过渡金属催化偶氮基导向的C(sp^2)—H键官能团化研究进展  

Progress in the Transition Metal-Catalyzed C(sp^2)—H Bond Functionalization of Azoarenes

作　　者：黄房生[1,2] 陈训[1] 谢应[1] 曾伟[1] 

机构地区：[1]华南理工大学化学与化工学院,广州510640 [2]英德市良仕工业材料有限公司,清远513059

出　　处：《有机化学》2017年第1期31-39,共9页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金(No.21372085);广州市科技计划项目(No.156300075);清远市科技计划(No.2014D006)资助项目~~

摘　　要：芳香偶氮化合物在有机染料、医药、蛋白探针和功能材料等领域应用广泛,高效构建偶氮功能化的芳烃衍生物是有机合成化学的研究热点领域之一.过渡金属催化偶氮基导向C(sp^2)—H键官能团化策略因可高区域选择性和高原子经济性地构建多样性芳基偶氮化合物而备受关注.对近年来过渡金属催化偶氮功能基导向的C—H键官能团化反应类型及相关反应机理予以论述,为后续研究提供参考.Developing simple and concise methods to construct azoarene derivatives has aroused wide concerns due to that these compounds are widely used in the fields of organic dyes, medicines, protein probe and functional materials. As a highly atom- and step-economical approach to making these compounds, transition metal-catalyzed azo group-directed C（sp2）—H bond functionalization provides an efficient synthetic method to regioselectively assemble azoarenes. The reaction types about diverse C（sp2）—H bond functionalzation of azoarenes were summarized in this paper.

关 键 词：芳基偶氮化合物 过渡金属催化 C(sp2)—H键官能化反应 导向功能基 

分 类 号：O621.251[理学—有机化学]