异山梨醇不同制备体系中强酸性催化剂研究进展  

Research Progress on Application of Strongly Acidic Catalysts and Preparation of Isosorbide

作　　者：于波[1,2] 刘世民[1] 丁万昱[1] 柴卫平[1] 蔡伟杰[3] 

机构地区：[1]大连交通大学,辽宁大连116028 [2]济南城建集团有限公司,山东济南250001 [3]大连工业大学,辽宁大连116034

出　　处：《广州化工》2017年第3期3-5,17,共4页GuangZhou Chemical Industry

基　　金：国家自然科学基金项目(No:21303185)

摘　　要：介绍了异山梨醇作为重要的生物质基材料的特点以及在医药、塑料、表面活性剂、聚合物等领域的应用,总结了传统山梨醇脱水制备异山梨醇反应体系中液体酸催化剂、固体酸催化剂和介孔酸催化剂的特点,指出液体酸催化剂的不足以及逐渐被绿色环保的固体酸催化剂和介孔酸催化剂所取代的趋势;同时本文还阐述了目前较为前沿的纤维素制备异山梨醇反应体系中纤维素"一锅法"制备异山梨醇及其催化剂研究现状,并指出了未来的研究热点和方向。The properties and application of isosorbide were discussed in the medicine,plastics,surfactant and polymer,etc. Both the reaction process of isosorbide production from sorbitol and the recent progress of catalysts（ liquid catalysts,solid catalysts and mesoporous catalyst） were summarized. The trend of the liquid acid catalyst replaced by the green solid acid catalyst and mesoporous acid catalyst was described. Meanwhile,a novel isosorbide synthesis from cellulose via one-pot reaction and its development were described. The review pointed out the research hotpot about the isosorbide production in the future.

关 键 词：异山梨醇 山梨醇 纤维素 强酸性催化剂 

分 类 号：O643.364[理学—物理化学]