TiO_2/漂珠对垃圾渗滤液吸附性能研究  

Study on adsorption property of TiO_2/float pearls on landfill leachate

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作  者:杨清[1] 许朋朋[1] 朱敬林[1] 刘少敏[1] 

机构地区:[1]安徽理工大学地球与环境学院,淮南232001

出  处:《化工新型材料》2017年第2期126-129,共4页New Chemical Materials

基  金:安徽理工大学博士基金(2012);安徽省国际合作项目(12030603003)

摘  要:为了研究TiO_2/漂珠对垃圾渗滤液吸附性能,通过SEM、XRD、FT-IR、BET对其结构进行表征,并探究了溶液起始浓度、起始pH、催化剂投加量对垃圾渗滤液吸附的影响。结果表明,当COD浓度为540mg/L,TiO_2/漂珠投加量为3g/L,pH=10时,垃圾渗滤液的TOC吸附量为5.03mg/g。研究还发现TiO_2/漂珠吸附动力学符合伪二级动力学方程,吸附过程大致分为3个阶段:在0~3h内,总有机碳(TOC)含量减少;在3~10h内,TOC含量增加;在10~24h内,吸附达到平衡。The adsorption properties of TiO2/float pearls on landfill leachate was discussed.The structure of TiO2/float pearls was characterized with SEM,XRD,FT-IR and BET,and the effects of the initial concentration,the dosage of TiO2/float pearls and the pH on the adsorption of landfill leachate were investigated.The results showed that the highest TOC capacity of landfill leachate was 5.03mg/g,when its pH was 10,the concentration of COD was 540mg/L and the dosage of catalyst was 3g/L.The research also found that the adsorption dynamics of TiO2/float pearls followed the pseudo second order kinetics,the adsorption process divided into three stages:the concentration of total organic carbon(TOC)was reduced within 0-3hours;the concentration of TOC was increased within 3-10hours;the adsorption reached balance within 10-24hours.

关 键 词:TiO2/漂珠 垃圾渗滤液 吸附 动力学 

分 类 号:X703[环境科学与工程—环境工程]

 

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