不同磷源等离子体制备高活性Ni_2P加氢脱硫催化剂  

Different phosphorus source for preparing highly active Ni_2P hydrodesulfurization catalyst by plasma

作　　者：王超[1] 王安杰[2,3] 李翔[2,3] 王伟[1,2] WANG Chao WANG An-jie LI Xiang WANG Wei(Yinchuan Energy Institute, Yinchuan 750105, Ningxia, China State Key Laboratory of Fine Chemical, Dalian University of Technology, Dalian 116012, Liaoning Province, China Liaoning Key Laboratory of Petrochemical Technology and Experiment, Dalian 116012, Liaoning Province, China)

机构地区：[1]银川能源学院,宁夏银川750105 [2]大连理工大学精细化工国家重点实验室,辽宁大连116012 [3]辽宁省省级高校石油化工技术与装备重点实验室,辽宁大连116012

出　　处：《化学工程》2017年第3期6-9,26,共5页Chemical Engineering(China)

基　　金：国家自然科学基金资助项目(21173033);宁夏自然科学基金资助项目(NZ15284);宁夏高校优秀青年教师培育基金资助项目(NGY2015209)

摘　　要：以氯化镍(硝酸镍)和次磷酸铵(磷酸氢二铵)(Ni:P摩尔比为1)为原料,氢等离子体还原法(PR)制备高活性加氢脱硫Ni_2P催化剂,新制备的催化剂在移入固定床反应器之前用质量分数10%H_2S/Ar钝化,以保护其结构不被破坏。以质量分数为0.8%的二苯并噻吩(DBT)/十氢萘溶液为模型化合物,考察了不同磷原催化剂的加氢脱硫(HDS)性能。X射线衍射(XRD)对制备的催化剂晶相进行了表征。实验证明,低价态P源制备的Ni_2P催化剂(N_2P-1-PR)的加氢脱硫(HDS)活性高于高价态P源制备的Ni_2P催化剂(N_2P-2-PR)。XRD表征结果表明,N_2P-1-PR粒度较小,导致其高活性增加。在Ni_2P催化剂上,DBT主要通过直接脱硫路径(DDS)。Ni2P highly active hydrodesulfurization（HDS） catalyst was prepared by the hydrogen plasma reduction （PR）, in which the precursors containing NiCl2 [ Ni （ NO3 ） ] and NH4H2PO2 [ （ NH4 ）2 HPO4 ] （ Ni： P mole ratio of 1） were directly converted to the active phosphide phase. A mixture of 10% H2S in Ar was used to passivate the freshly synthesized Ni2P to protect their crystal structures before entering fixed bed reactor. The HDS performances of different phosphorus source catalysts were studied using a model fuel containing mass fraction 0. 8% dibenzothiophene in decalin, and the morphologies of the catalysts were characterized by X-ray diffraction （XRD）. The catalytic activity was compared Ni2 p with phosphate as raw materials by the hydrogen plasma reduction. The results show that hydrodesulfurization （HDS） activity of the NizP catalyst（ N2P-1-PR） prepared with low state P source is higher than the Ni2P catalyst（N2P-2-PR） prepared with high state P source. The XRD characterization results reveal that particle size of N2P-1-PR is less than N2P-2-PR, which increases its highly active. The DBT was mainly through the path of DDS desulfurization over the NizP catalyst.

关 键 词：P源 氢等离子体 NI2P 催化剂 

分 类 号：O643.36[理学—物理化学]