二聚脂肪酸基UV／湿热双重固化树脂单体的研究  

Study on the UV/wet heating dual-curing resin monomer based on the dimer fatty acids

作　　者：毛伟 李守海[1,2] 杨雪娟[1] 曹珊 汪梅[1] 夏建陵[1,2] MAO Wei LI Shou-hai YANG Xae-juan CAO Shan WANG Mei XIA Jian-ling(Institute of Chemical Industry of Forestry Products, CAF,Key Lab. of Biomass Energy and Material, Jiangsu Province, National Engineering Lab. for Biomass Chemical Utilization , Key and Lab. on Forest Chemical Engineering, SFA, Nanjing 210042, China Institute of Forest New Technology, CAF, Beijing 100091, China)

机构地区：[1]中国林业科学研究院林产化学工业研究所,生物质化学利用国家工程实验室,国家林业局林产化学工程重点开放性实验室,江苏省生物质能源与材料重点实验室,江苏南京210042 [2]中国林业科学研究院林业新技术研究所,北京100091

出　　处：《热固性树脂》2017年第2期12-16,31,共6页Thermosetting Resin

基　　金：中国林科院基本科研专项资金项目(CAFINT2014C08);国家十二五科技支撑项目(2015BAD15B04)资助

摘　　要：采用二聚脂肪酸(DA)、甲基丙烯酸缩水甘油酯(GMA)和异氰酸丙基三乙氧基硅烷(IPTS)为原料制得双固化树脂单体DA-GMA-IPTS,FTIR分析结果表明目标产物成功合成。将制得的DA-GMA-IPTS单体单独湿热固化、先UV光固化后湿热固化及先湿热固化后UV光固化制得固化材料,对其进行力学性能、硬度、动态热机械分析和热重分析,结果表明,与DA-GMA单体UV固化材料相比,先UV光固化后湿热固化得到的固化材料综合性能最为优异,拉伸强度、玻璃化转变温度及热初始分解温度可分别达到14.40 MPa,50.95℃和320℃,双固化方式明显优于单一的固化方式。A dual-curing resin monomer named DA-GMA-IPTS was synthesized using dimer fatty acids （DA）, glycidyl methacrylate （GMA） and isocyanate propyl triethoxy silane （IPTS） as materials. The FTIR analysis results showed that the target product was successfully synthesized. The three cured materials were obtained by single wet and heat curing, first UV curing and then wet heat curing, first wet heat curing and then UV curing. The products were investigated by the testings of mechanical properties and hardness, dynamic thermomechanical analysis and thermogravimetrie analysis. The results showed that the curing material cured with first UV curing and then wet heat curing method had the best comprehensive properties compared with the DA-GMA cured material with single UV curing method. The tensile strength, glass-transition temperatures and initial thermal decomposition temperature of cured material was up to 14.40 MPa, 50.95℃ and 320 ℃, repectively. The dual-curing method was significantly better than a single euring method.

关 键 词：二聚脂肪酸 uV湿热双重固化 树脂单体 拉伸强度 热稳定性 

分 类 号：TQ320.1[化学工程—合成树脂塑料工业]