超支化环氧树脂改性苯并口恶嗪树脂的制备与性能  

Preparation and Properties of Benzoxazine with Hyperbranched Epoxy Modifier

作　　者：靳奇峰[1] 谭荔元 佟丽娜[1] 姜冬月 蹇锡高[2] 

机构地区：[1]辽宁师范大学化学化工学院,辽宁大连116021 [2]大连理工大学高分子材料系,辽宁大连116012

出　　处：《高分子材料科学与工程》2017年第3期150-154,共5页Polymer Materials Science & Engineering

基　　金：辽宁省博士启动基金资助项目(20111066)

摘　　要：采用兼有脂肪族和芳香族结构的超支化环氧树脂(HBER)增韧改性苯并口恶嗪树脂(MDA),制备出不同质量比的MDA/HBER均相共混体系。通过傅里叶变换红外光谱、差示扫描量热及动态力学性能分析仪研究了共混体系固化行为和交联网络结构。利用流变仪对共混体系进行动态黏度测试,结果表明在60~190℃之间出现一段较宽的低黏度平台。力学性能测试表明,当HBER质量分数为10%时,共混固化物弯曲性能最优,韧性最佳。共混固化物断面形貌呈现出原位增韧增强特征。Hyperbranched polyether epoxy （HBER） with combination of aliphatic-aromatic moieties was incorporated at different concentrations into an aromatic benzoxazine （MDA） network without cure-induced phase separation. The architecture and mechanical properties of resulting homogeneous network were studied through FT-IR, DSC and DMA. The viscosity of the blend which was measured by rheometer maintains a minimum between 60--190 ℃. The mechanical properties tests show that the hyperbranched structure allows for simultaneous enhancement in both flexural property and impact toughness as the HBER mass fraction reaches 10% in the blend. The fracture surface morphology of the cured blend shows characteristics of in-situ toughness enhancement.

关 键 词：苯并噁嗪 超支化环氧树脂 共混 增韧 

分 类 号：TQ323.5[化学工程—合成树脂塑料工业]