羟甲基膦酰杂环状苯基硫代膦酸酯化合物的合成与应用研究  

Synthesis and Application of Hydroxymethyl-phosphono Hetero Cyclic Phenyl Phosphorothioate Compounds

作　　者：王彦林[1] 王世杰[1] 陆赞 杨珂珂[1] 

机构地区：[1]苏州科技大学化学生物与材料工程学院,苏州215009

出　　处：《塑料助剂》2017年第1期23-26,共4页Plastics Additives

摘　　要：以三羟甲基氧化膦和苯基硫代膦酰二氯为主要原料,制备了有机硫-磷阻燃剂1-硫代-4-氧代-1-苯基-4-羟甲基-2,6-二氧杂-1,4-二磷杂环己烷(ODPRSP)。研究了主要反应因素,确定适宜的反应条件为n(三羟甲基氧化磷)∶n(苯基硫代膦酰二氯)为1∶1,反应在90℃保温反应3 h、115℃保温反应6 h。产率达95.3%。通过FTIR,~1H-NMR,差热分析及极限氧指数等技术表征了产物的结构及性能。在不饱和树脂中的应用表明ODPRSP具有良好的阻燃性能。An organic sulfur-phosphine flame retardant, 1-thio-4-oxo-l-phenyl-4-hydroxymethyl-2,6-dioxa- 1,4-dioxaphosphorinane （ODPRSP） , was synthesized from tris （ hydroxymethyl ） phosphine oxide and benzene phosphorus thiodichloride. By studying on the main reaction factors, the optimal conditions were selected as fol- lows： n（C3 H904 P）：n（ C6H5 C12 PS）is 1： 1, the first step going at 90℃ for 3 h,the second step going at 115℃ for 6 h and the yield can reach to 95.3%. The structure and properties of the resultant were character- ized by means of FYIR, 1 H - NMR,TG analysis and LOI test. Application of the unsaturated resin showed that ODPRSP had good flame retardant properties.

关 键 词：硫-磷阻燃剂 三羟甲基氧化磷 苯基硫代膦酰二氯 

分 类 号：TQ314.248[化学工程—高聚物工业]