新型π共轭有机氟硼络合物的研究进展  

Research progress on the new π-conjugated organic fluoroboron complexes

作　　者：尹振明[1] 刘丽娟[2] 李彤[3] 

机构地区：[1]天津师范大学化学学院,天津300387 [2]天津师范大学无机-有机杂化功能材料化学教育部重点实验室,天津300387 [3]天津师范大学天津市功能分子结构与性能重点实验室,天津300387

出　　处：《天津师范大学学报（自然科学版）》2017年第2期1-7,16,共8页Journal of Tianjin Normal University：Natural Science Edition

基　　金：国家自然科学基金资助项目(21172174)

摘　　要：π共轭有机氟硼络合物作为重要的荧光染料之一,以其较高的荧光量子产率和较大的摩尔吸光系数、良好的化学和光学稳定性备受关注,在有机合成、药物化学、新型材料、生命科学等领域应用广泛.本文综述了近年来π共轭有机氟硼络合物的合成研究,主要是N,N二齿、O,O二齿和N,O二齿类络合物,介绍了一些重要化合物的结构特点、主要性能及应用情况.π-conjugated organic fluoroboron complexes, as a kind of important fluorophores, have been the focus of in- tense research for their higher quantum yields, larger extinction coefficients, outstanding chemo-stability and photo stabi- lity in recent years. They have been widely used in various fields, such as organic synthesis, pharmaceutical chemistry, new material and bioscience. This paper reviews the synthesis of some novel π-conjugated organic fluoroboron complexes, mainly including N, N-bidentates, 0,0-bidentates and N, O-bidentates. Some important complexes were introduced on their structure features, main characteristics and applications.

关 键 词：有机氟硼络合物 荧光分子探针 分子识别 氟离子 

分 类 号：O627[理学—有机化学]