金属纳米颗粒光散射特性研究  

THE STUDY OF THE METAL NANOPARTICLE LIGHT SCATTERING

作　　者：张宇杰[1] 杨仕娥[1] 陈永生[1] 郜小勇[1] 谷锦华[1] 卢景霄[1] 

机构地区：[1]郑州大学物理工程学院材料物理教育部重点实验室,郑州450052

出　　处：《太阳能学报》2017年第3期721-725,共5页Acta Energiae Solaris Sinica

基　　金：国家重点基础研究发展(973)计划(2011CB201606);国家自然科学基金(11204276)

摘　　要：采用基于有限元的数值模拟方法,建立微晶硅衬底上单个金属纳米颗粒与光相互作用的三维(3D)模型,分别计算不同半径的Ag、Al、Au和Cu球状纳米颗粒的散射截面、吸收截面、散射效率及耦合效率。结果表明:随着金属纳米球半径R的增大,表面等离激元偶极共振峰发生红移且展宽,同时颗粒的归一化吸收截面快速下降;在中长波段(500~1100 nm),颗粒的散射效率随R的增大而增大,但耦合效率则呈现单调下降趋势。在相同尺寸的Ag、Al、Au和Cu颗粒中,Au和Cu的吸收截面较大,当R=50 nm时,Au和Cu颗粒的吸收截面甚至大于其散射截面,二者在中短波段(300~550 nm)的散射效率明显偏低。另外,金属纳米颗粒的耦合效率对颗粒成分变化不敏感。In this paper, we investigated the light scattering properties of the metal nanoparticle above the microcrystalline silicon （μc-Si） substrate with 3D numerical model via the finite element method. The normal scattering cross section, normal absorption cross section, scattering efficiency and coupling efficiency of Au, Ag, A1 and Cu nanoparticle with different size were calculated. The results showed that with the nanoparticle size increasing, metal surface plasmon dipole resonance wavelength is red-shifted, the resonance peak can also be broadened, and the absorption cross section decreases rapidly. The larger size increases the scattering efficiency at the wavelength range of 500-1100 nm, otherwise, leads to the decrease of the coupling efficiency. The absorption of Au and Cu particle is greater than Ag and A1 at the same size. When R=50 nm, the absorption cross section of Au and Cu is even greater than the scattering cross section so that the scattering efficiency is low clearly at the wavelength range of 300-550 nm. Besides, the coupling efficiency is not sensitive to the nanoparticle component.

关 键 词：金属纳米颗粒 表面等离激元共振 光散射 太阳电池陷光 

分 类 号：TB383.1[一般工业技术—材料科学与工程]