多孔液体新型材料研究及应用进展  

Progresses in exploration and application of porous liquid materials

作　　者：李彦霖 段尊斌 霍添 朱丽君[1] 项玉芝[1] 夏道宏[1] 

机构地区：[1]中国石油大学(华东)化学工程学院,重质油国家重点实验室,山东青岛266580

出　　处：《化工进展》2017年第4期1342-1350,共9页Chemical Industry and Engineering Progress

摘　　要：多孔液体材料指的是内部单元分子具有稳定的、永久性的、形状固定的空腔结构的一类液体,它突破了多孔固体材料不具备流动性所带来的储存和应用等系列问题。本文回顾了多孔液体这一新型材料的研究背景,概述了其最新研究进展。依据多孔液体材料内部单元分子结构的不同将其分为两大类,并详细介绍了其分子结构特点与制备方法。对制备多孔液体材料的物质特性进行了归纳,阐述了多孔液体材料在气体吸附、气体分离、主客体化学等方面的应用进展。最后对其未来发展前景进行了展望,多孔液体材料有望应用于催化、石油化工、光电材料、生物学等领域,其合成和应用将成为人们研究的热点。Porous liquid materials refer to a certain type of liquids with internal unit molecular possessing stable, permanent, shape fixed cage cavities, which overcome the storage and application limitations of porous solid materials. In this paper, the background of porous liquid materials was firstly reviewed, and the development of the materials was presented. Then, according to different structure features, the porous liquid materials were classified into two categories, and theirs preparation methods were given in detail. Moreover, the applications of porous liquid materials include gas adsorption and separation as well as host-guest chemistry. At last, the future development of them was prospected. Porous liquid materials are expected to be used in areas of catalysis, photoelectric material, petrochemical industry, and biology. The synthesis and application of porous liquid materials will become a research focus.

关 键 词：多孔液体材料 制备 化学反应 结构特征 吸附 分离 

分 类 号：O641.3[理学—物理化学]