咪唑类氮杂环卡宾金属配合物的合成与应用研究进展  

Recent Advances in Syntheses and Applications of Imidazole N-Heterocyclic Carbene Metal Complexes

作　　者：郭芳杰[1] 郭亚楠[1] 夏立娜 孙京[1] 

机构地区：[1]辽宁石油化工大学化学与材料科学学院,抚顺113001 [2]中国石油天然气股份有限公司锦州石化分公司,锦州121001

出　　处：《化学通报》2017年第4期329-333,共5页Chemistry

基　　金：辽宁石油化工大学引进人才科研启动基金(2016XJJ-006);新疆兵团化工绿色过程重点实验室-省部共建国家重点实验室培育基地项目(KF201601)资助

摘　　要：氮杂环卡宾具有独特的结构和性质,可合成大量的氮杂环卡宾金属化合物,现在已发展为催化领域的重要配体之一,一直受到大量研究者的关注。本文综述了以咪唑作为基本单元搭载不同的杂原子基团合成一系列具有单齿、双齿和多齿型金属螯合物的方法及其在Suzuki偶联、Heck偶联等反应中的应用。N-Heterocyclic carbenes （NHC） can be used to synthesize a variety of heterocyclic carbene metal compounds due to its unique structure and properties. Now NHC has been developed as one of the most important ligands in the field of catalysis and has been the focus of a large number of researchers. The synthesis methods of metal complexes with monodentate, bidentate and multidentate using imidazole as the basic unit equipped with different heteroatomic groups were reviewed in this paper, and their applications in the Suzuki coupling reaction, Heek coupling reactions were also summarized.

关 键 词：N-杂环卡宾 螯合型化合物 合成 应用 

分 类 号：O621.251[理学—有机化学]