分散染料neocron black(NB)的生物降解特性  

Degradation of the Disperse Dye Neocron Black(NB) by Biological Treatment

作　　者：杨波[1,2] 丁凤友 徐辉[1,2] 李方[1,2] 田晴[1,2] 马春燕[1,2] 

机构地区：[1]国家环境保护纺织工业污染防治工程技术中心,上海201620 [2]东华大学环境科学与工程学院,上海201620

出　　处：《环境科学》2017年第4期1520-1528,共9页Environmental Science

基　　金：上海市自然科学基金项目(13ZR1401000)

摘　　要：在好氧、厌氧、好氧/厌氧交替条件下,采用活性污泥系统生物处理分散染料neocron black(NB),研究分散染料NB在需氧或者厌氧状态下的生物降解特性以及外加碳源对其生物降解特性的影响,并全波段扫描和气相色谱-质谱联用(GC-MS),初步探讨该染料的生物降解过程.结果表明,NB染料在好氧条件下降解效率最高,厌氧/好氧交替条件次之,厌氧条件下染料降解效率最低.随着NB染料浓度的增加,由于染料和中间代谢产物的抑制作用,微生物对染料的降解效率逐渐下降.添加易生物降解碳源可以促进NB染料的生物降解过程,并改变生物降解过程的动力学特征.全波段扫描和GC-MS测定结果显示,NB染料经过生物降解作用后,发色基团得到较彻底降解,NB染料生物降解中间产物有2,4-二硝基苯胺、2-氰基-4-硝基苯胺、对硝基苯胺等.The biodegradation characteristics of the azo disperse dye neocron black（NB） were investigated under aerobic,anaerobic and anaerobic/aerobic conditions separately with the activated sludge system,and the biological degradation process of the dye was analyzed by spectrophotometry and gas chromatography mass spectrometry（GC-MS）.The results showed that the degradation efficiency of NB dye was the highest under fully aerobic conditions,followed by the anaerobic/aerobic conditions,and fully anaerobic condition was the lowest.With the increase of the concentration of NB dye,the dye and the intermediate metabolite greatly decreased the microbial degradation efficiency of NB dye.The addition of carbon source could not only promote the biodegradation of NB dye,but also change the kinetic characteristics of the biodegradation process.The spectrophotometry and GC-MS determination results showed that the chromophore was completely degraded after biodegradation of NB dye.The intermediates metabolites of NB dye included 2,4-Dinitroaniline,2-cyano-4-nitro aniline,p-Nitroaniline etc.

关 键 词：分散染料 neocron black(NB) 生物降解 好氧 厌氧 好氧/厌氧交替 

分 类 号：X703.1[环境科学与工程—环境工程]