Yb^(3+)/Ho^(3+)掺杂纳米氟磷灰石的制备及发光性质研究  

Preparation and Luminescent Properties of Yb^(3+)/Ho^(3+) Doped Nano-fluorapatite

作　　者：张钦涵 邹鹏[1] 刘丽炜[1] 胡思怡[1] 任玉[1] 王玥[1] 房文汇[1] 张喜和[1] 

机构地区：[1]长春理工大学理学院,长春130022

出　　处：《长春理工大学学报（自然科学版）》2017年第1期38-42,共5页Journal of Changchun University of Science and Technology(Natural Science Edition)

基　　金：长春理工大学科技创新基金(XJJLG-2015-01)

摘　　要：利用水热法成功制备了Yb^(3+)/Ho^(3+)掺杂氟磷灰石(FA:Yb^(3+)/Ho^(3+))纳米材料,通过改变稀土离子Yb^(3+)的掺杂比例有效提高了纳米材料的上转换发光强度。利用透射电子显微镜(TEM)、X射线衍射仪(XRD)、傅里叶红外光谱仪(FTIR)、荧光光谱仪等表征手段对Yb^(3+)/Ho^(3+)掺杂纳米氟磷灰石的形貌、结晶程度和物相组成、发光性质进行了研究。结果表明,Yb^(3+)/Ho^(3+)掺杂氟磷灰石纳米材料呈棒状并具有六方相结构。通过对稀土离子Yb^(3+)的掺杂比例进行调节,使得材料的上转换发光效率有了明显的增强,Yb^(3+)的掺杂含量为60%时发光最强。因此,这类具有较好上转换发光性能的FA:Yb^(3+)/Ho^(3+)纳米材料可为细胞标记和成像提供良好的条件,有望促进其在生物医药领域中的广泛应用。Yb3＋/Ho3＋ doped nano-fluorapatite （FA： Yb3＋/Ho3＋）were prepared successfully by hydrothermal method. The up- conversion luminescence intensity of FA：Yb3＋/Ho3＋ nanomaterials were effectively improved by changing the doped pro- portion of the rare earth Yb3＋ ions. Transmission electron microscopy （TEM）,X-ray diffraction （XRD）,Fourier Trans- form Infrared Spectrometer （FTIR）, fluorescence spectroscopy were used to characterization the morphology, degree of crystallinity and phase composition, luminescence properties of Yb3＋/Ho3＋ doped nano-fluorapatite. The results showed that Yb3＋/Ho3＋ doped nano-hydroxyapatite material rod-shaped and has a hexagonal crystal structure. By adjusting the doped proportion of the rare earth Yb3＋ ions, upconversion luminescence efficiency of the material has greatly improved. The strongest emitting of FA：Yb3＋/Ho3＋ nanomaterials is when the doped proportion of the rare earth Yb3＋ ions reach to 60%. Thus,this kind of FA：Yb3＋/Ho3＋ nanomaterials has good upeonversion luminescence properties can provide fa- vorable conditions in cell markers and imaging. It is expected to promote their wider application in the biomedical field.

关 键 词：Yb3+、Ho3+掺杂 纳米氟磷灰石 上转换发光 

分 类 号：TQ133.3[化学工程—无机化工]