Diffusion Characteristic of Sulfate Anion in Surface Region of Cement Mortar at Early Stage  

作　　者：王学兵 潘志华 SHEN Xiaodong CHEN Yangyi LIU Weiqing 

机构地区：[1]College of Materials Science and Engineering, Nanjing Tech University, Nanjing 210009, China [2]College of Civil Engineering, Nanjing Tech University, Nanjing 210009, China

出　　处：《Journal of Wuhan University of Technology(Materials Science)》2017年第2期358-364,共7页武汉理工大学学报（材料科学英文版）

基　　金：Funded by the Major State Basic Research Development Program of China(No.2011CB013800)

摘　　要：The SO4^（2-）concentration distributions in surface region of cement mortar immersed in sulfate solution at early stage were measured by layered sampling method combined with chemical analysis, and the diffusion coefficients of SO4^（2-）anions in surface region of mortar into internal area were calculated by means of instantaneous plane diffusion theory. The experimental results showed that the SO4^（2-）concentration gradually reduced when the diffusion depth increased in the surface region of mortar. Diffusion coefficient（D） was relevant with the concentration and kind of environmental sulfate solution, which reduced with immersion time at the beginning, and then rose slowly after a period of time. The calculation of initial diffusion coefficient（D0） and starting time of deterioration（t∞） caused by sulfate attack was further attempted based on the data of diffusion coefficient, and it was found that D0 and t∞ were all relevant with concentrations of sulfate and different kind of sulfate as well.The SO4^（2-）concentration distributions in surface region of cement mortar immersed in sulfate solution at early stage were measured by layered sampling method combined with chemical analysis, and the diffusion coefficients of SO4^（2-）anions in surface region of mortar into internal area were calculated by means of instantaneous plane diffusion theory. The experimental results showed that the SO4^（2-）concentration gradually reduced when the diffusion depth increased in the surface region of mortar. Diffusion coefficient（D） was relevant with the concentration and kind of environmental sulfate solution, which reduced with immersion time at the beginning, and then rose slowly after a period of time. The calculation of initial diffusion coefficient（D0） and starting time of deterioration（t∞） caused by sulfate attack was further attempted based on the data of diffusion coefficient, and it was found that D0 and t∞ were all relevant with concentrations of sulfate and different kind of sulfate as well.

关 键 词：cement mortar sulfate attack diffusion coefficient 

分 类 号：TQ177.62[化学工程—硅酸盐工业]