大气预锈对混凝土模拟液中低合金钢筋腐蚀行为的影响  

Influence of Atmospheric Pre-rusting on Corrosion Behavior of Low-Alloy Rebar in Simulated Concrete Pore Solution

作　　者：施锦杰[1] 明静[1] 王丹芊 孙伟[1] 

机构地区：[1]东南大学江苏省土木工程材料重点实验室,江苏南京211189

出　　处：《建筑材料学报》2017年第2期180-185,共6页Journal of Building Materials

基　　金：江苏省产学研联合创新基金资助项目(BY2013091);国家重点基础研究发展计划(973计划)项目(2015CB655100);国家自然科学基金资助项目(51208098;51678144)

摘　　要：通过电化学阻抗谱(EIS)、背散射电子(BSE)图像与能谱分析(EDS)研究了大气预锈对低合金钢筋和普通低碳钢筋在混凝土模拟液中氯盐腐蚀行为的影响.结果表明:大气预锈作用影响2种钢筋钝化膜的生成;氯盐侵蚀后,大气预锈作用降低了低碳钢筋的耐蚀性,但低合金钢筋的耐蚀性不受预锈作用影响,原因是低合金钢筋基体与氧化皮间的缝隙内形成了致密的富Cr锈层,抑制了氯盐对钢筋基体的进一步侵蚀.The influence of atmospheric pre-rusting on the chloride-induced corrosion behaviors of low-alloy （LA） rebar and conventional low-carbon（LC） rebar in simulated concrete pore sohtion（SCPS） was inves- tigated using electrochemical impedance spectroscopy（EIS） and surface analysis techniques （BSE images and EDS analysis）. The results indicate that, the formation of passive film for both rebars is slightly influ- enced by pre-rusting and the reduced corrosion resistance of LC rebar can be observed after chlorides at- tack. However, the long-term chloride-induced corrosion behavior of LA rebar is not affected by pre-rus- ting. The main reason is that compact Cr-enriched corrosion products are gradually formed for LA rebar, thus fill the crevice between rebar substrate and prevent from the further attack by chlorides.

关 键 词：预锈 低合金钢筋 混凝土模拟液 电化学阻抗谱 背散射电子图像 

分 类 号：TG174.3[金属学及工艺—金属表面处理]