废旧轮胎热解炭黑与SiO2并用在丁苯橡胶中的应用研究  

Application Research of Combination of SiO_2/Carbon Black pyrolyed with Waste Tires to SBR

作　　者：周作艳 夏琳[1] 辛振祥[1] 王军晓[2] 朱永宁[2] 

机构地区：[1]青岛科技大学橡塑材料与工程教育部重点实验室,青岛266042 [2]苏州宝化炭黑有限公司,江苏苏州215000

出　　处：《特种橡胶制品》2017年第2期5-9,共5页Special Purpose Rubber Products

基　　金：国家自然科学基金委员会青年科学基金项目,项目编号:51303092,51273098;山东省高等学校科技计划项目,项目编号:J14LA12

摘　　要：研究了废旧轮胎热解炭黑(简称:热解炭黑)与二氧化硅(SiO_2)在丁苯橡胶中的应用情况,考察了二者不同配比对丁苯橡胶混炼胶的动态力学性能、门尼粘度、硫化特性以及硫化胶力学性能、磨耗性能、导电性能的影响。结果表明,加入SiO_2可使混炼胶Payne效应增强,粘度升高,硫化时间延长;当热解炭黑/SiO_2配比为50/10和45/5时,硫化胶拉伸强度和撕裂强度均最优;配比为50/5时耐磨性能最好;随着填料总用量的增大,硫化胶导热性能升高。Application of combination of SiO2 and carbon black pyrolyed with waste tires to SBR was researhed.The effects of different compounding ratioes of SiO2 and the pyrolytic carbon black on dynamic mechanical properties,Mooney viscosity,curing characteristics,mechanical properties,abrasion resistance and electrical conductive were discussed.The results showed that the Payne effect was increased by adding SiO2,the viscosity rose,the curing time was prolonged.The tensile strength and the tear strength were optimal when the compounding ratioes of the pyrolytic carbon black and SiO2 were 50/10 or 45/5.The wear resistance was the best when the compounding ratioes was 50/5.The thermal conductivity was enhanced with the increase of total amount of fillers.

关 键 词：废旧轮胎热解炭黑 丁苯橡胶 SIO2 导电性 RPA 

分 类 号：TQ333.1[化学工程—橡胶工业]