光学活性聚酰胺酰亚胺的合成研究进展  

Research Advance on Synthesis of Optically Active Poly(amide-imide)s

作　　者：许杰[1] 杨云峰[1] 李宇飞[1] 刘亚坚[1] 

机构地区：[1]中北大学理学院,太原030000

出　　处：《工程塑料应用》2016年第12期136-140,共5页Engineering Plastics Application

摘　　要：介绍了光学活性聚酰胺酰亚胺的3种主要合成方法,即酰氯法、二异氰酸酯法及亚胺二羧酸法,讨论并总结了三种方法的优缺点,综述了以D–氨基酸和L–氨基酸为手性源的光学活性聚酰胺酰亚胺的合成研究现状,介绍了光学活性聚酰胺酰亚胺的性能如旋光性、热稳定性及可生物降解性等。Three synthetic methods of optically active poly（amide-imide）s including the methods of acyl chloride, diisocyanate and imide-diacid were described, and both the advantages and disadvantages of these methods were discussed. The present status on synthesis of optically active poly（amide-imide）s derived from L-amino acids and D-amino acids were reviewed. The performance of optically active poly（amide-imide）s were introduced such as optical rotation, thermal stability and biodegradability and so on.

关 键 词：光学活性 聚酰胺酰亚胺 合成方法 研究进展 

分 类 号：O631.5[理学—高分子化学]