二茂铁基非线性光学材料研究进展  

Progress of ferrocenyl functionalized materials with nonlinear optical response

作　　者：汪徐春[1,2] 肖陆飞[2] 吴杰颖[2] 李胜利[2] 田玉鹏[2] 

机构地区：[1]安徽科技学院化学与材料工程学院,安徽蚌埠233100 [2]安徽大学化学化工学院,安徽合肥230601

出　　处：《安徽大学学报（自然科学版）》2017年第3期28-34,共7页Journal of Anhui University(Natural Science Edition)

基　　金：国家自然科学基金资助项目(51432001;51672002);安徽省人才基金资助项目(GXFXZD2016176);安徽省教育厅自然科学基金重点资助项目(KJ2016A171;KJ2016A184)

摘　　要：二茂铁衍生物由于具有独特的双环夹心结构和高度的电子离域特点,使其具有优良的非线性光学效应、氧化还原可逆性和特殊稳定性等.文中从结构和性能等方面介绍二茂铁基新型金属有机材料的研究现状,着重介绍电化学和非线性光学活性的二茂铁衍生物的研究进展.引用二茂铁在电化学和非线性光学发展史上具有代表性的论文,旨在帮助读者了解二茂铁功能材料的研究进展,把握其前沿动态.Ferrocene derivatives exhibit promising nonlinear optical （NLO） response, electrochemical reversibility, and special stability, owing to their ＂sandwich structure＂ and high n-electron delocalization. The recent progress on new metal organic ferrocenyl derivative materials was reviewed in the respect with their structures and properties, especially for their electrochemical and NLO derivatives were remarked in the optics, which may help the readers ferrocenyl materials. properties. Representative publications of ferrocenyl developing history of electron chemical and nonlinear to understand the developing and frontier of functional ferrocenyl materials.

关 键 词：二茂铁 非线性光学 电化学 功能化 

分 类 号：O627.81[理学—有机化学]