玫瑰红作用下γ-六氯环己烷在冰相中的光敏化降解  

Rose Bengal-sensitized Photolysis of γ-Hexachlorocyclohexane in Ice

作　　者：陈柏言[1] 康春莉[1] 武家玉 王依雪 郭志新[1] 包思琪[1] 钟宇博 田涛[1] 薛洪海[3] 

机构地区：[1]吉林大学地下水资源与环境教育部重点实验室,长春130012 [2]太原工业学院环境与安全工程系,太原030008 [3]吉林建筑大学松辽流域水环境教育部重点实验室,长春130118

出　　处：《高等学校化学学报》2017年第5期791-797,共7页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金(批准号:41073063,41403101)资助~~

摘　　要：考察了在玫瑰红(RB)存在下γ-六氯环己烷(γ-HCH)在冰中的光降解.结果表明,光敏剂RB通过其激发态[RB]~*及其产生的~1O_2~*加速了γ-HCH的光降解,RB浓度是影响光降解率最显著的因素;γ-HCH在较低初始浓度下的光敏化降解更快;无机盐离子的种类和浓度可以改变冰表面上类液层(LLL)的比例从而影响γ-HCH的光解.通过分析γ-HCH光降解产物提出了RB存在时冰中γ-HCH的光降解作用机理.Rose bengal （ RB ） -sensitized photolysis of gamma-hexachlorocyclohexane （γ-HCH ） in ice was investigated. The results show that the photosensitizer RB accelerate the photolysis of γ-HCH by the excited state [ RB ] ＊ and its product singlet oxygen （1O2 ＊ ）, and RB concentration is the most significant factor affecting the photolysis rate; the sensitized photolysis of γ-HCH at lower initial concentrations on the μg/L scale is faster; the type and concentration of inorganic salts can change the proportion of liquid like layer （LLL） on the surface of ice and thus affect the photolysis of γ-HCH. Based on the results above, the photo- products were analyzed and the sensitized photolysis mechanism of γ-HCH in the presence of RB was pro- posed.

关 键 词：γ-六氯环己烷 玫瑰红 冰 光降解 

分 类 号：O644[理学—物理化学]