成纤性粉煤灰的低熔区组成及分布  

Compositions and distribution of fly ash in low-melting zone

作　　者：吴萍萍[1] 张泽武[2] 陈建定[1] 

机构地区：[1]华东理工大学材料科学与工程学院,上海200237 [2]华东理工大学工程设计研究院,上海200237

出　　处：《化工学报》2017年第5期1767-1772,共6页CIESC Journal

基　　金：国家自然科学基金项目(21476083)~~

摘　　要：粉煤灰的熔融温度分布图对粉煤灰成纤的降熔配比具有指导意义。利用X荧光光谱仪和灰熔点测试仪,分别测得5种不同来源粉煤灰样品的组成和熔融特性温度。运用实验所测值与117种粉煤灰组成及熔融温度的文献值,以Al_2O_3+SiO_2、CaO+Mg O、Fe_2O_3+TiO_2为三相坐标制成三元相图,按照熔融温度高低划分不同区域,得到粉煤灰熔融温度分布图,找出低熔区(流动温度FT<1350℃)的组成及其组成与熔融温度的分布规律。同时将次要组分通过等电量换算后标在CaO-Al_2O_3-SiO_2三元相图中,发现所研究粉煤灰在低熔区的组成与CaO-Al_2O_3-SiO_2三元相图中1350℃低温共熔区的组成具有良好的一致性,由此找出高熔融温度粉煤灰成纤的降熔调配方法。The melting temperature distribution of fly ash used to prepare fiber is a key to the composition ratio for reducing the melting temperature. Using X-ray fluorescence spectrometry and ash fusion point determination meter, the compositions and fusion temperature of five kinds of fly ash samples were measured. Ternary phase diagram with A1203＋SiO2, CaO＋MgO, Fe203＋TiO2 for three-phase coordinate was obtained based on the experimental results in the present study and the data of compositions and melting temperature of 117 fly ash samples in literature. Meanwhile, the fly ash melting temperature profile was derived from the zoning method according to different melting temperature. With the effort of distinguishing the compositions of fly ash in low-melting zone, the regularities of its compositions and melting temperature have been established. It has been proved that the compositions and distribution of fly ash in the low melting regions （FT〈1350℃） are well consistent with the low melting point regions of 1350℃ in CaO-A1203-SiO2 ternary phase diagrams where the minor components are converted to the equal charge of main components, leading to a method of reducing the melting temperature of the fly ash with high melting temperature.

关 键 词：粉煤灰 低熔区 三元相图 熔融温度 氧化铝 二氧化硅 

分 类 号：TB321[一般工业技术—材料科学与工程]