Facile synthesis and characterization of acetate intercalated Co-La layered double hydroxide  

作　　者：Meenakshi Pokhriyal Sitharaman Uma Rajamani Nagarajan 

机构地区：[1]Materials Chemistry Group, Department of Chemistry, University of Delhi

出　　处：《Journal of Rare Earths》2017年第5期474-479,共6页稀土学报（英文版）

基　　金：Project supported by DST(SB/S1/PC-08/2012);Govt. of India and University of Delhi under the “Scheme to Strengthen R&D Doctoral Research Program” and DU-DST PURSE Grant

摘　　要：Layered double hydroxide（LDH） comprising of Co^2＋ and La^3＋-ions with acetate counter anion was successfully synthesized by hydrogen peroxide catalyzed hydrolysis reaction and characterized extensively. The observed reflections in the powder X-ray diffraction pattern could be indexed in P3 space group with a=0.316 nm and c=2.97 nm. Lattice fringes of distances corresponding to the peaks observed in X-ray diffraction pattern were observed in high resolution transmission electron microscopic images. UV-visible diffuse reflectance spectroscopy results confirmed the presence of Co（OH）6 along with the presence of charge-transfer band due to the interlayer carboxylate anion. Magnetization measurements at room temperature indicated high spin configuration of Co^2＋-ion in the sample exhibiting paramagnetic behavior. The mixed metal oxide from calcination was used to reconstruct the parent layered structure. Intercalation experiments with other organic anions in Co-La LDH proved be successful.Layered double hydroxide（LDH） comprising of Co^2＋ and La^3＋-ions with acetate counter anion was successfully synthesized by hydrogen peroxide catalyzed hydrolysis reaction and characterized extensively. The observed reflections in the powder X-ray diffraction pattern could be indexed in P3 space group with a=0.316 nm and c=2.97 nm. Lattice fringes of distances corresponding to the peaks observed in X-ray diffraction pattern were observed in high resolution transmission electron microscopic images. UV-visible diffuse reflectance spectroscopy results confirmed the presence of Co（OH）6 along with the presence of charge-transfer band due to the interlayer carboxylate anion. Magnetization measurements at room temperature indicated high spin configuration of Co^2＋-ion in the sample exhibiting paramagnetic behavior. The mixed metal oxide from calcination was used to reconstruct the parent layered structure. Intercalation experiments with other organic anions in Co-La LDH proved be successful.

关 键 词：layered acetate interlayer hydroxide hydrolysis anion calcination carboxylate reconstruct intercalation 

分 类 号：O611.64[理学—无机化学]