无固化剂环氧树脂乳液对油井水泥早期水化的影响  

Influence of Epoxy Resin Emulsion Without Curing Agent on Hydration of Oil Well Cement in Early Age

作　　者：阎培渝[1] 岳蕾[1] 代丹[2] 罗宇维[2] 

机构地区：[1]清华大学土木工程系,北京100084 [2]中海油田服务股份有限公司,河北燕郊065201

出　　处：《硅酸盐学报》2017年第5期608-613,共6页Journal of The Chinese Ceramic Society

基　　金：国家自然科学基金项目(No.51678344;No.51678343)

摘　　要：将不同聚合度环氧树脂乳液以不同掺量掺加到固井水泥浆中,制备环氧树脂乳液改性水泥浆。在无固化剂、不同温度条件下,通过水化热测量,扫描电子显微镜,X射线衍射等方法研究了环氧树脂乳液对油井水泥早期水化特性的影响。结果表明:相对于纯油井水泥浆体,环氧树脂水泥浆的水化进程被延缓,但是水化产物没有明显变化,环氧树脂在硬化水泥浆体中主要以聚合物膜的形式存在,可填充水泥石内部的毛细孔隙,使环氧树脂水泥石的抗压强度随着环氧树脂掺量的提高而略有增加。Epoxy resin modified cement pastes containing different percentages of emulsion were prepared using two kinds of epoxy resin emulsions with different polymerization degrees. The influence of epoxy resin emulsion without curing agent on the early hydration process of oil well cement pastes was investigated at different temperatures using isothermal hydration heat evolution, scanning electron microscopy and X-ray diffraction. The results show that the hydration process of epoxy resin modified cement pastes is delayed, compared to that of blank cement pastes, while their hydration products are similar. There is an epoxy resin film wrapping the particles in hardened cement pastes, which can fill of cement stones increases slightly as the content of epoxy resin the capillary pores of cement stones. Hence, the compressive strength emulsion increases.

关 键 词：环氧树脂乳液 水泥浆 水化过程 水化产物 抗压强度 

分 类 号：TE256[石油与天然气工程—油气井工程]