天然植物葡萄为原料制备5-羟甲基糠醛的初步研究  

Preliminary study on the preparation of 5-hydroxymethylfurfural from grapes

作　　者：陈明鸽[1] 葛振红[1] 吴胜利[1] 唐雪娇[1] 席蓝萍 高寒[1] 田维亮[1,2] 

机构地区：[1]塔里木大学新疆兵团南疆化工资源利用工程实验室生命科学学院,新疆阿拉尔市843300 [2]北京化工大学化工资源有效利用国家重点实验室,北京100029

出　　处：《现代化工》2017年第5期120-122,共3页Modern Chemical Industry

基　　金：兵团高等学校优秀青年教师培养计划项目;北京化工大学化工资源有效利用国家重点实验室开放课题(CRE-2012-C-105);塔里木大学校长基金(TDZKSS201204)

摘　　要：根据国内外有关5-羟甲基糠醛(5-HMF)制备的研究进展,利用天然植物葡萄为原料制备5-HMF。实验结果表明,铜离子影响氯化铬的催化效果,产率显著降低,酸性基团硅钨酸在氯化铬的催化体系影响甚微,没有提高催化效果;葡萄液制备5-羟甲基糠醛的最佳工艺条件:反应温度为120℃,反应时间为2 h,葡萄液∶二甲基亚砜(体积比)=1∶5,通过反应溶液的置换,能够提高5-HMF产率,产率可达36%。该方法可以促进5-HMF制备成本的降低,推进其产业化进程。Based on global research progress on the preparation of 5-hydroxymethylfurfural（ 5-HMF）,5-HMF has been prepared by using natural grape as raw material. The experimental result shows that copper ion affects catalytic effect of chromium chloride,causing the yield of 5-HMF to drop significantly. But acid group silicotungstic acid has little influence on catalytic effect of chromium chloride,which cannot improve catalytic effect too. The optimum conditions of preparing 5-HMF from grape include that temperature is 120℃,reaction time is 2 h,and the volume ratio of grape solution to dimethyl sulfoxide is 1∶ 5. The replacement of reaction solution can improve the yield of 5-HMF to 36%. The production cost of 5-HMF can be cut down through using natural plant liquid as raw materials,promoting its industrialization.

关 键 词：5-羟甲基糠醛 葡萄 复合催化 

分 类 号：TQ251.11[化学工程—有机化工]