CO_2催化加氢制备甲醇的研究进展  

Progresses in the research for the catalytic hydrogenation of carbon dioxide to methanol

作　　者：张香玲[1] 马清祥[1] 赵天生[1] 耿梦倩 李鹏[1] Zhang Xiangling Ma Qingxiang Zhao Tiansheng Geng Mengqian Li Peng(State Key Laboratory of High-efficiency Coal Utilization and Green Chemical Engineering, College of Chemistry and Chemical Engineering, Ningxia University, Yinchuan Ningxia 750021, China)

机构地区：[1]宁夏大学化学化工学院省部共建煤炭高效利用与绿色化工国家重点实验室,宁夏银川750021

出　　处：《石油化工》2017年第5期637-642,共6页Petrochemical Technology

基　　金：国家自然科学基金项目(21466030);宁夏科技支撑计划项目(2015BY113);宁夏自然科学基金项目(NZ13044)

摘　　要：CO_2催化加氢合成甲醇是实现CO_2有效利用的理想途径之一,而高效催化剂是提高反应转化率和选择性的关键所在。概述了CO_2加氢合成甲醇的反应历程和催化作用机理,讨论了催化活性中心Cu粒子的价态、晶面结构和组分对催化性能的影响,总结了ZnO的作用及形貌的影响,归纳了CO_2加氢制甲醇催化剂载体和助剂的作用,比较了各种催化剂制备方法的优缺点。The catalytic hydrogenation of carbon dioxide to methanol is considered as one of the ideal ways to utilize carbon dioxide effectively, and the efficient catalysts are the key for increasing the conversion of carbon dioxide and the selectivity to methanol. In this paper, the catalytic reaction mechanism for the catalytic hydrogenation was summarized. The influences of the valence state, crystal structure and composition of copper-based catalysts on the catalyst performances were discussed, and the effects of ZnO as cocatalyst and support on the performances of the Cu/ZnO catalysts were analyzed. The advantages and disadvantages of the preparation methods were introduced.

关 键 词：甲醇 C02加氢 催化加氢 反应机理 

分 类 号：TQ426[化学工程]