(H_2Biz)_2[ZnO_6(As_3O_3)_2Mo_6O_(18)]的水热合成及晶体结构与性质研究  

The Research on the Synthesis and Crystal Structure of(H_2Biz)_2[ZnO_6(As_3O_3)_2Mo_6O_(18)]

作　　者：夏林 苏占华[1,2] 赵志凤 周百斌[1,2] 马秀娟 丛博文[1,2] Xia Lin Su Zhanhua Zhao Zhifeng Zhou Baibin Ma Xiujuan Cong Bowen(Key Laboratory of Synthesis of Functional Materials and Green Catalysis, Colleges of Heilongjiang Province, Harbin Normal Universit)

机构地区：[1]功能材料的设计合成与绿色催化黑龙江省高校重点实验室 [2]哈尔滨师范大学

出　　处：《哈尔滨师范大学自然科学学报》2016年第5期60-64,共5页Natural Science Journal of Harbin Normal University

摘　　要：利用水热合成技术,选择低毒NaAsO_2为起始原料,通过调节反应物浓度、控制反应温度、反应时间等方法合成了一种以{MAs_6Mo_6}为基本框架的砷钼酸盐,通过元素分析、IR、TG、和X-射线衍射对晶体结构进行了表征,对该化合物的性质进行了初步研究.Using the hydrothermal synthesis technology, low toxicity to choose NaAsO2 as the starting material, by adjusting the concentration of reactants, control of reaction temperature and time, an arsenmolybdate used { MAs6Mo6} t as a basic framework is synthetized. The arsenmolybdate are characterizedby elemental analysis, IR, TG, and X - ray diffraction on the crystal structure and the properties of the the compounds are studied.

关 键 词：砷钼酸盐 水热合成 晶体结构 

分 类 号：O173[理学—数学]