高效率制备超导涂层导体SmBiO_3缓冲层  

High-Efficient Preparation of SmBiO_3 Buffer Layer for Superconducting Coated Conductors

作　　者：朱晓垒[1,2] 蒲明华[1,2] 张红[1,2] 赵勇[1,2] ZHU Xiaolei;PU Minghua;ZHANG Hong;ZHAO Yong(Key Laboratory of Advanced Technologies of Materials,Ministry of Education,Southwest Jiaotong University,Chengdu 610031,China;Superconductivity and New Energy R&D Center,Southwest Jiaotong University,Chengdu 610031,China)

机构地区：[1]西南交通大学材料先进技术教育部重点实验室,四川成都610031 [2]西南交通大学超导与新能源研究开发中心,四川成都610031

出　　处：《西南交通大学学报》2017年第3期633-638,共6页Journal of Southwest Jiaotong University

基　　金：国家自然科学基金资助项目(NSFC51377138;NSFC51072168)

摘　　要：为了缩短高温超导涂层导体缓冲层薄膜制备周期,采用自开发的前驱溶液,以乳酸为溶剂,硝酸钐和硝酸铋为溶质,在应由表面氧化外延法所得的衬底(NiO(l00)/NiW)上,用化学溶液沉积快速制备了SmBiO_3缓冲层薄膜,研究成相温度对SmBiO_3薄膜的影响;在SmBiO_3薄膜上沉积YBa_2Cu_3O_7-δ超导层,检验其效用.研究结果表明:在798.5℃下制备的SmBiO_3缓冲层薄膜平整致密,并且高度织构,缓冲层薄膜制备周期缩短到2h以内;在SmBiO_3上所沉积的超导层薄膜超导转变温度为89K,超导临界电流密度为1.46MA/cm2(77K、0T),达到了某些电力应用要求;该SmBiO_3薄膜制备方法可用于高温超导涂层导体的快速制备.In order to shorten the preparation period of buffer layer for high-performance coated conductors, SmBi03 （ SBO） buffer films were efficiently deposited on surface-oxidation epitaxy processed NiO （ 100 ）/NiW substrates by chemical solution deposition （ CSD ） method, using a precursor solution prepared by dissolving samarium nitrate and bismuth nitrate precursors in lactic acid. The effect of sintering temperature on the SBO film was systematically studied. Then, the YBa2Cu307_8（ YBCO） superconductive film was deposited on the SBO buffer layer to test its utility. Results show that a highly textured, smooth and dense SBO thin film was obtained at 798. 5 °C , and the SBO thin film could be prepared within a period of less than 2 h. The YBCO superconductive layer was successfully deposited on the SBO layer with a superconducting transition temperature of 89 K and a critical current density of 1.46 MA/cm2（77 K, 0 T） , which could be used in some electric power applications. Therefore, the proposed method for preparing SBO buffer layer can be used for rapid preparation of coated conductors.

关 键 词：涂层导体 高效化学溶液沉积 SmBiO3缓冲层 

分 类 号：R318.08[医药卫生—生物医学工程]