水溶性氮杂环卡宾金属配合物的研究进展  

Research Progress in Water-Soluble N-Heterocyclic Carbene Metal Complexes

作　　者：郭芳杰[1] 郭亚楠[1] 田睿 孙京[1] Guo Fangjie Guo Yanan Tian Rui Sun Jing(Faculty of Chemistry and Material Science, Liaoning Shihua University, Fushun 113001)

机构地区：[1]辽宁石油化工大学化学与材料科学学院,抚顺113001

出　　处：《化学通报》2017年第6期533-538,共6页Chemistry

基　　金：辽宁石油化工大学引进人才科研启动基金(2016XJJ-006);新疆兵团化工绿色过程重点实验室-省部共建国家重点实验室培育基地项目(KF201601)资助

摘　　要：氮杂环卡宾(NHCs)金属配合物作为一类重要的催化剂一直是有机合成领域研究的热点。近年来,通过引入水溶性配体而得到的水溶性氮杂环卡宾过渡金属配合物受到广大科研工作者的青睐。本文主要总结了水溶性NHCs的分类、合成及其在C-C偶联反应、复分解反应以及催化加氢反应中的应用,并对水溶性NHCs金属配合物的发展趋势进行了展望。N-Heteroeyclic earbene （NHCs） metal complexes as a class of significant catalysts have been a hot research field in organic synthesis. In recent years, water-soluble NCHs transition metal complexes obtained by the introduction of water-soluble ligands have attracted more and more attention from researchers. In this paper, the classification and syntheses of water-soluble NHCs and their application in the C-C coupling reaction, metathesis reaction and catalytic hydrogenation were summarized, and the development trend of water-soluble NHCs metal complexes was also discussed.

关 键 词：水溶性 氮杂环卡宾 过渡金属配合物 合成 

分 类 号：O641.4[理学—物理化学]