两种新的联吡啶钌光敏染料的合成及表征  

Synthesis and Characterization of Two New Ruthenium Bipyridine Photosensitive Dyes

作　　者：张立攀 郭青照 任钊 王永 Zhang Lipan Guo Qingzhao Ren Zhao Wang Yong(Henan Commerce Science Inst itute Co. Ltd. ？Zhengzhou 45000)

机构地区：[1]河南省商业科学研究所有限责任公司,郑州450002

出　　处：《河南师范大学学报（自然科学版）》2017年第4期62-66,共5页Journal of Henan Normal University(Natural Science Edition)

基　　金：中科院河南省省院合作项目(102106000030)

摘　　要：以2,2’-联吡啶取代物为原料,设计合成了两种新的具有不同配体的联吡啶钌光敏染料;利用红外吸收光谱和核磁共振氢谱对各光敏染料及其中间物进行了结构表征.研究了两种光敏染料的光伏性能,结果表明两者性能良好:两者在可见光区分别存在最大吸收波长521nm和545nm,带隙计算值分别为1.87eV和1.58eV;将它们制成DSSCs器件,在模拟太阳光照射下(AM1.5),其能量转换效率分别达到了10.21%和9.97%.Two new ruthenium bipyridine photosensitive dyes with different ligands were synthesized from substituted 2, 2？-bipyridine. The structures of the dyes and their intermediates were characterized by IR and 1HNMR. The photophysical and electrochemical properties of the dyes were studied, and the results were satisfactory： the maximum absorption wave -lengths in the visible region of them were 521 nm and 545 nm, and the calculated values of the band gaps were 1. 87 eV and 1. 58 eV. The photoelectric conversion efficiencies of the dyes based DSSCs werelO. 21% and 9. 97%.

关 键 词：联吡啶钌 光敏染料 合成 染料敏化太阳能电池 光电转化效率 

分 类 号：O625.6[理学—有机化学]