Preparation and Reactions of Perfluoroalkanesulfenyl Chlorides  

作　　者：Ze-Feng Xu Min Jiang Jin-Tao Liu 

机构地区：[1]Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China [2]Department of Chemistry, Zhejiang Sci-Tech University, Xiasha West Higher Education District, Hangzhou, Zhejiang 310018, China

出　　处：《Chinese Journal of Chemistry》2017年第4期442-446,共5页中国化学（英文版）

基　　金：We thank the National Natural Science Foundation of China （No. 21572257 and 21502213） and Shanghai Sailing Program （No. 15YF1414800） for financial support.

摘　　要：Several perfluoroalkanesulfenyl chlorides were prepared from the corresponding perfluoroalkanesulfenic acids in high yields, and their reactions with thiol, amine, arene and alkene were studied. A series of perfluoroal- kyl-containing disulfides, sulfonamides, aryl sulfides and a-chlorosulfides were synthesized under mild conditions.Several perfluoroalkanesulfenyl chlorides were prepared from the corresponding perfluoroalkanesulfenic acids in high yields, and their reactions with thiol, amine, arene and alkene were studied. A series of perfluoroal- kyl-containing disulfides, sulfonamides, aryl sulfides and a-chlorosulfides were synthesized under mild conditions.

关 键 词：perfluoroalkanesulfenyl chloride perfluoroalkanesulfenyl acid SUBSTITUTION DISULFIDE ADDITION 

分 类 号：TQ153.15[化学工程—电化学工业] TQ028.8